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CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes
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- Title
- CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes
- Author(s)
- Xiangya Xu; Pooi B.; Hirao H.; Hong S.H.
- Subject
- conformation analysis · hydrogen bonds ·noncovalent interactions · palladium · p interactions
- Publication Date
- 2014-01
- Journal
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.53, no.5, pp.1283 - 1287
- Publisher
- WILEY-V C H VERLAG GMBH
- Abstract
- The role of CH-π and CF-π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH-π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF-π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1- pentafluorophenylimidazol-2-ylidene) palladium(II). © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
- ISSN
- 1433-7851
- Appears in Collections:
- Center for Nanoparticle Research(나노입자 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- 1283_ftp.pdfDownload
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