CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes
DC Field | Value | Language |
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dc.contributor.author | Xiangya Xu | - |
dc.contributor.author | Pooi B. | - |
dc.contributor.author | Hirao H. | - |
dc.contributor.author | Hong S.H. | - |
dc.date.available | 2015-04-20T06:23:13Z | - |
dc.date.created | 2014-08-11 | - |
dc.date.issued | 2014-01 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/1162 | - |
dc.description.abstract | The role of CH-π and CF-π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH-π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF-π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1- pentafluorophenylimidazol-2-ylidene) palladium(II). © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. | - |
dc.description.uri | 1 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.subject | conformation analysis · hydrogen bonds ·noncovalent interactions · palladium · p interactions | - |
dc.title | CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000336504500013 | - |
dc.identifier.scopusid | 2-s2.0-84893944953 | - |
dc.identifier.rimsid | 309 | ko |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Xiangya Xu | - |
dc.identifier.doi | 10.1002/anie.201309371 | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.53, no.5, pp.1283 - 1287 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 53 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 1283 | - |
dc.citation.endPage | 1287 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 19 | - |
dc.description.scptc | 21 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | π interactions | - |
dc.subject.keywordAuthor | Conformation analysis | - |
dc.subject.keywordAuthor | Hydrogen bonds | - |
dc.subject.keywordAuthor | Noncovalent interactions | - |
dc.subject.keywordAuthor | Palladium | - |