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CH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes

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dc.contributor.authorXiangya Xu-
dc.contributor.authorPooi B.-
dc.contributor.authorHirao H.-
dc.contributor.authorHong S.H.-
dc.date.available2015-04-20T06:23:13Z-
dc.date.created2014-08-11-
dc.date.issued2014-01-
dc.identifier.issn1433-7851-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/1162-
dc.description.abstractThe role of CH-π and CF-π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH-π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF-π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1- pentafluorophenylimidazol-2-ylidene) palladium(II). © 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.description.uri1-
dc.language영어-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectconformation analysis · hydrogen bonds ·noncovalent interactions · palladium · p interactions-
dc.titleCH-π and CF-π interactions lead to structural changes of n-heterocyclic carbene palladium complexes-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000336504500013-
dc.identifier.scopusid2-s2.0-84893944953-
dc.identifier.rimsid309ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorXiangya Xu-
dc.identifier.doi10.1002/anie.201309371-
dc.identifier.bibliographicCitationANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.53, no.5, pp.1283 - 1287-
dc.citation.titleANGEWANDTE CHEMIE-INTERNATIONAL EDITION-
dc.citation.volume53-
dc.citation.number5-
dc.citation.startPage1283-
dc.citation.endPage1287-
dc.date.scptcdate2018-10-01-
dc.description.wostc19-
dc.description.scptc21-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordAuthorπ interactions-
dc.subject.keywordAuthorConformation analysis-
dc.subject.keywordAuthorHydrogen bonds-
dc.subject.keywordAuthorNoncovalent interactions-
dc.subject.keywordAuthorPalladium-
Appears in Collections:
Center for Nanoparticle Research(나노입자 연구단) > 1. Journal Papers (저널논문)
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