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The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor
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- Title
- The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor
- Author(s)
- Ye Ji Kim; Kim, SM; Hosono, H; Yang, JW; Sung Wng Kim
- Subject
- alcohol, ; aldehyde, ; ammonia, ; calcium, ; electride, ; methanol, ; nitrogen, ; organic solvent, ; article, ; chemical bond, ; chemical reaction, ; electron, ; electron transport, ; electrophilicity, ; organic chemistry, ; pinacol coupling reaction
- Publication Date
- 2014-05
- Journal
- CHEMICAL COMMUNICATIONS, v.50, no.37, pp.4791 - 4794
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N]+·e- as an electron donor in organic solvents. The bond cleavages of the [Ca2N] + layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe) 2 and ammonia. © The Royal Society of Chemistry 2014.
- ISSN
- 1359-7345
- Appears in Collections:
- Center for Integrated Nanostructure Physics(나노구조물리 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- 341. 2014_ChemComm_-_Ca2N_-_Yeji.pdfDownload
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