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나노 구조 물리 연구단
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The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor

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Title
The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor
Author(s)
Ye Ji Kim; Kim, SM; Hosono, H; Yang, JW; Sung Wng Kim
Publication Date
2014-05
Journal
CHEMICAL COMMUNICATIONS, v.50, no.37, pp.4791 - 4794
Publisher
ROYAL SOC CHEMISTRY
Abstract
The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N]+·e- as an electron donor in organic solvents. The bond cleavages of the [Ca2N] + layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe) 2 and ammonia. © The Royal Society of Chemistry 2014.
URI
https://pr.ibs.re.kr/handle/8788114/1021
ISSN
1359-7345
Appears in Collections:
Center for Integrated Nanostructure Physics(나노구조물리 연구단) > Journal Papers (저널논문)
Files in This Item:
341. 2014_ChemComm_-_Ca2N_-_Yeji.pdfDownload

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