BROWSE

Related Scientist

cinap's photo.

cinap
나노구조물리연구단
more info

ITEM VIEW & DOWNLOAD

The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor

Cited 27 time in webofscience Cited 27 time in scopus
1,252 Viewed 238 Downloaded
Title
The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor
Author(s)
Ye Ji Kim; Kim, SM; Hosono, H; Yang, JW; Sung Wng Kim
Subject
alcohol, ; aldehyde, ; ammonia, ; calcium, ; electride, ; methanol, ; nitrogen, ; organic solvent, ; article, ; chemical bond, ; chemical reaction, ; electron, ; electron transport, ; electrophilicity, ; organic chemistry, ; pinacol coupling reaction
Publication Date
2014-05
Journal
CHEMICAL COMMUNICATIONS, v.50, no.37, pp.4791 - 4794
Publisher
ROYAL SOC CHEMISTRY
Abstract
The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N]+·e- as an electron donor in organic solvents. The bond cleavages of the [Ca2N] + layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe) 2 and ammonia. © The Royal Society of Chemistry 2014.
URI
https://pr.ibs.re.kr/handle/8788114/1021
DOI
10.1039/c4cc00802b
ISSN
1359-7345
Appears in Collections:
Center for Integrated Nanostructure Physics(나노구조물리 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
341. 2014_ChemComm_-_Ca2N_-_Yeji.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse