The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ye Ji Kim | - |
dc.contributor.author | Kim, SM | - |
dc.contributor.author | Hosono, H | - |
dc.contributor.author | Yang, JW | - |
dc.contributor.author | Sung Wng Kim | - |
dc.date.available | 2015-04-20T05:53:41Z | - |
dc.date.created | 2014-09-11 | - |
dc.date.issued | 2014-05 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/1021 | - |
dc.description.abstract | The scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N]+·e- as an electron donor in organic solvents. The bond cleavages of the [Ca2N] + layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe) 2 and ammonia. © The Royal Society of Chemistry 2014. | - |
dc.description.uri | 1 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.subject | alcohol | - |
dc.subject | aldehyde | - |
dc.subject | ammonia | - |
dc.subject | calcium | - |
dc.subject | electride | - |
dc.subject | methanol | - |
dc.subject | nitrogen | - |
dc.subject | organic solvent | - |
dc.subject | article | - |
dc.subject | chemical bond | - |
dc.subject | chemical reaction | - |
dc.subject | electron | - |
dc.subject | electron transport | - |
dc.subject | electrophilicity | - |
dc.subject | organic chemistry | - |
dc.subject | pinacol coupling reaction | - |
dc.title | The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000334735700004 | - |
dc.identifier.scopusid | 2-s2.0-84898604844 | - |
dc.identifier.rimsid | 53044 | ko |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Ye Ji Kim | - |
dc.contributor.affiliatedAuthor | Sung Wng Kim | - |
dc.identifier.doi | 10.1039/c4cc00802b | - |
dc.identifier.bibliographicCitation | CHEMICAL COMMUNICATIONS, v.50, no.37, pp.4791 - 4794 | - |
dc.citation.title | CHEMICAL COMMUNICATIONS | - |
dc.citation.volume | 50 | - |
dc.citation.number | 37 | - |
dc.citation.startPage | 4791 | - |
dc.citation.endPage | 4794 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 14 | - |
dc.description.scptc | 16 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | BOND-FORMING REACTIONS | - |
dc.subject.keywordPlus | BIRCH REDUCTION | - |
dc.subject.keywordPlus | C-C | - |
dc.subject.keywordPlus | THEORETICAL APPROACH | - |
dc.subject.keywordPlus | STABLE ELECTRIDE | - |
dc.subject.keywordPlus | ANIONS | - |
dc.subject.keywordPlus | RADICALS | - |
dc.subject.keywordPlus | CARBON | - |
dc.subject.keywordPlus | STABILITIES | - |