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The scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor

DC Field Value Language
dc.contributor.authorYe Ji Kim-
dc.contributor.authorKim, SM-
dc.contributor.authorHosono, H-
dc.contributor.authorYang, JW-
dc.contributor.authorSung Wng Kim-
dc.date.available2015-04-20T05:53:41Z-
dc.date.created2014-09-11-
dc.date.issued2014-05-
dc.identifier.issn1359-7345-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/1021-
dc.description.abstractThe scalable pinacol coupling reaction is realized utilizing the inorganic electride [Ca2N]+·e- as an electron donor in organic solvents. The bond cleavages of the [Ca2N] + layers by methanol play a vital role in transferring anionic electrons to electrophilic aldehydes, accompanying the formation of Ca(OMe) 2 and ammonia. © The Royal Society of Chemistry 2014.-
dc.description.uri1-
dc.language영어-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectalcohol-
dc.subjectaldehyde-
dc.subjectammonia-
dc.subjectcalcium-
dc.subjectelectride-
dc.subjectmethanol-
dc.subjectnitrogen-
dc.subjectorganic solvent-
dc.subjectarticle-
dc.subjectchemical bond-
dc.subjectchemical reaction-
dc.subjectelectron-
dc.subjectelectron transport-
dc.subjectelectrophilicity-
dc.subjectorganic chemistry-
dc.subjectpinacol coupling reaction-
dc.titleThe scalable pinacol coupling reaction utilizing the inorganic electride [Ca2N](+)center dot e(-) as an electron donor-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000334735700004-
dc.identifier.scopusid2-s2.0-84898604844-
dc.identifier.rimsid53044ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorYe Ji Kim-
dc.contributor.affiliatedAuthorSung Wng Kim-
dc.identifier.doi10.1039/c4cc00802b-
dc.identifier.bibliographicCitationCHEMICAL COMMUNICATIONS, v.50, no.37, pp.4791 - 4794-
dc.citation.titleCHEMICAL COMMUNICATIONS-
dc.citation.volume50-
dc.citation.number37-
dc.citation.startPage4791-
dc.citation.endPage4794-
dc.date.scptcdate2018-10-01-
dc.description.wostc14-
dc.description.scptc16-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusBOND-FORMING REACTIONS-
dc.subject.keywordPlusBIRCH REDUCTION-
dc.subject.keywordPlusC-C-
dc.subject.keywordPlusTHEORETICAL APPROACH-
dc.subject.keywordPlusSTABLE ELECTRIDE-
dc.subject.keywordPlusANIONS-
dc.subject.keywordPlusRADICALS-
dc.subject.keywordPlusCARBON-
dc.subject.keywordPlusSTABILITIES-
Appears in Collections:
Center for Integrated Nanostructure Physics(나노구조물리 연구단) > 1. Journal Papers (저널논문)
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341. 2014_ChemComm_-_Ca2N_-_Yeji.pdfDownload

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