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Fe-catalyzed acceptorless dehydrogenation of secondary benzylic alcohols

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Title
Fe-catalyzed acceptorless dehydrogenation of secondary benzylic alcohols
Author(s)
Hansoo Song; Byungjoon Kang; Soon Hyeok Hong
Publication Date
2014-09
Journal
ACS CATALYSIS, v.4, no.9, pp.2889 - 2895
Publisher
AMER CHEMICAL SOC
Abstract
Oxidation of alcohols is an essential organic reaction, affording versatile carbonyl groups. To provide a sustainable solution for environmentally harmful traditional oxidation methods, the transition-metal catalyzed acceptor-free dehydrogenation of alcohols has attracted much attention. The widely used catalysts for the dehydrogenation reaction are based on precious metals, which are not economical and environmentally benign. We developed an operationally simple, economical, and environmentally benign acceptorless Fecatalyzed dehydrogenation of various secondary benzylic alcohols to afford the corresponding ketones and H2. A simple in situ mixture of readily available Fe(III) acetylacetonate, 1,10-phenanthroline, and K2CO3 was identified as an active catalyst for this transformation.
URI
https://pr.ibs.re.kr/handle/8788114/918
ISSN
2155-5435
Appears in Collections:
Center for Nanoparticle Research(나노입자 연구단) > Journal Papers (저널논문)
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