Oxygen atom transfer: a mild and efficient method for generating iminyl radicals

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Title
Oxygen atom transfer: a mild and efficient method for generating iminyl radicals
Author(s)
Kim, Y; Bielawski, CW; Eunsung Lee
Publication Date
2019-06
Journal
CHEMICAL COMMUNICATIONS, v.55, no.49, pp.7061 - 7064
Publisher
ROYAL SOC CHEMISTRY
Abstract
Treating iminoxyl species with oxygen acceptors such as PPh3 resulted in oxygen atom transfer and afforded the corresponding iminyl radicals. DFT and other calculations revealed that association between the oxygen atom acceptors and the iminoxyl species results in the formation of key intermediates during the reaction. Subsequent dissociation is accompanied with homolytic cleavage of the N-O bond and generates iminyl radicals with spin densities that are localized on exocyclic nitrogen atoms. ©The Royal Society of Chemistry 2019
URI
https://pr.ibs.re.kr/handle/8788114/6154
ISSN
1359-7345
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > Journal Papers (저널논문)
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