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첨단연성물질 연구단
첨단연성물질 연구단
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Uniform and directional growth of centimeter-sized single crystals of cyclodextrin-based metal organic frameworks

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Title
Uniform and directional growth of centimeter-sized single crystals of cyclodextrin-based metal organic frameworks
Author(s)
Namhun Kim; Jun Heuk Park; Jan Paczesny; Bartosz A. Grzybowski
Publication Date
2019-03
Journal
CRYSTENGCOMM, v.21, no.12, pp.1867 - 1871
Publisher
ROYAL SOC CHEMISTRY
Abstract
Although macroscopically-sized MOF crystals have proven of interest for efficient chromatographic separations, information processing, or optoelectronic devices, growing really large crystals has proven problematic and the largest reported monocrystals are only ca. 0.025 cm(3) in volume. Here, we report a sequential vapour-diffusion/reseeding procedure that yields monocrystals of -cyclodextrin (-CD) MOFs with volumes reaching 1 cm(3). With such large monoliths at hand, it is possible to physically block their certain faces and thus guide further growth only in desired directions, ultimately producing crystals of low-symmetry shapes and - upon doping with different additives at different stages of growth - with spatially varying compositions. © The Royal Society of Chemistry 2019
URI
https://pr.ibs.re.kr/handle/8788114/5880
ISSN
1466-8033
Appears in Collections:
Center for Soft and Living Matter(첨단연성물질 연구단) > Journal Papers (저널논문)
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1903_Bartosz_CrystEngComm_Uniform and directional growth of centimeter-sized single crystals of cyclodextrin-based metal organic frameworks.pdfDownload

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