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Uniform and directional growth of centimeter-sized single crystals of cyclodextrin-based metal organic frameworks

DC Field Value Language
dc.contributor.authorNamhun Kim-
dc.contributor.authorJun Heuk Park-
dc.contributor.authorJan Paczesny-
dc.contributor.authorBartosz A. Grzybowski-
dc.date.available2019-07-19T05:38:27Z-
dc.date.created2019-04-22-
dc.date.issued2019-03-
dc.identifier.issn1466-8033-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/5880-
dc.description.abstractAlthough macroscopically-sized MOF crystals have proven of interest for efficient chromatographic separations, information processing, or optoelectronic devices, growing really large crystals has proven problematic and the largest reported monocrystals are only ca. 0.025 cm(3) in volume. Here, we report a sequential vapour-diffusion/reseeding procedure that yields monocrystals of -cyclodextrin (-CD) MOFs with volumes reaching 1 cm(3). With such large monoliths at hand, it is possible to physically block their certain faces and thus guide further growth only in desired directions, ultimately producing crystals of low-symmetry shapes and - upon doping with different additives at different stages of growth - with spatially varying compositions. © The Royal Society of Chemistry 2019-
dc.description.uri1-
dc.language영어-
dc.publisherROYAL SOC CHEMISTRY-
dc.titleUniform and directional growth of centimeter-sized single crystals of cyclodextrin-based metal organic frameworks-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000462635300005-
dc.identifier.scopusid2-s2.0-85063102089-
dc.identifier.rimsid67855-
dc.contributor.affiliatedAuthorNamhun Kim-
dc.contributor.affiliatedAuthorJun Heuk Park-
dc.contributor.affiliatedAuthorJan Paczesny-
dc.contributor.affiliatedAuthorBartosz A. Grzybowski-
dc.identifier.doi10.1039/c9ce00026g-
dc.identifier.bibliographicCitationCRYSTENGCOMM, v.21, no.12, pp.1867 - 1871-
dc.citation.titleCRYSTENGCOMM-
dc.citation.volume21-
dc.citation.number12-
dc.citation.startPage1867-
dc.citation.endPage1871-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusMOF CRYSTALS-
dc.subject.keywordPlusREMOVAL-
dc.subject.keywordPlusRELEASE-
dc.subject.keywordPlusBINDING-
dc.subject.keywordPlusSTORAGE-
dc.subject.keywordPlusDESIGN-
dc.subject.keywordPlusFILMS-
Appears in Collections:
Center for Soft and Living Matter(첨단연성물질 연구단) > 1. Journal Papers (저널논문)
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1903_Bartosz_CrystEngComm_Uniform and directional growth of centimeter-sized single crystals of cyclodextrin-based metal organic frameworks.pdfDownload

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