An Organic Mixed-Valence Ligand for Multistate Redox-Active Coordination Networks

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Title
An Organic Mixed-Valence Ligand for Multistate Redox-Active Coordination Networks
Author(s)
Ha, JY; Jin Young Koo; Ohtsu, H; Yakiyama, Y; Kimoon Kim; Hashizume, D; Kawano, M
Publication Date
2018-04
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.17, pp.4717 - 4721
Publisher
WILEY-V C H VERLAG GMBH
Abstract
The multistate redox-active/multi-interactive ligand 5,5,8,8-tetra(4-pyridyl)-2,2-(1,4-phenylene)bis-1H-perimidine (H2TPP) was designed and synthesized. H2TPP undergoes four one-electron oxidation steps, and was used for the preparation of a multistate redox-active coordination network in a solid-liquid interface reaction using molten Cd2+ salts. The multiple redox states of H2TPP were confirmed spectroscopically by stepwise four-electron oxidation. Spectroscopic analysis indicated that the mixed-valence states of the ligand are class II on the UV/Vis/NIR timescale and borderline class II/class III on the ESR timescale. (c) 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/5790
ISSN
1433-7851
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > Journal Papers (저널논문)
Center for Artificial Low Dimensional Electronic Systems(원자제어 저차원 전자계 연구단) > Journal Papers (저널논문)
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