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IBS Publications RepositoryCenter for Self-assembly and Complexity(복잡계 자기조립 연구단)1. Journal Papers (저널논문)
SuFEx in Metal-Organic Frameworks: Versatile Postsynthetic Modification Tool
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- Title
- SuFEx in Metal-Organic Frameworks: Versatile Postsynthetic Modification Tool
- Author(s)
- Seungjae Park; Hayoung Song; Nakeun Ko; Kim, C; Kimoon Kim; Eunsung Lee
- Subject
- metal-organic frameworks, ; postsynthetic modification, ; SuFEx chemistry, ; click chemistry, ; heterogeneous catalysis
- Publication Date
- 2018-10
- Journal
- ACS APPLIED MATERIALS & INTERFACES, v.10, no.40, pp.33785 - 33789
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A new type of click reaction, sulfur(VI) fluoride exchange (SuFEx), has been utilized to prepare five postsynthetically modified UiO-67 series metal-organic frameworks (MOFs). The postsynthetic modification (PSM) via SuFEx can be achieved selectively for the sulfonyl fluoride (R-SO2F) without degrading the MOF structure as confirmed by X-ray crystallographic analysis. The present SuFEx method provides a straightforward tool for introducing new functionality inside MOFs. Introduction of an imidazolium group into the MOF afforded a heterogeneous catalyst for the benzoin condensation reaction. © 2018 American Chemical Society
- ISSN
- 1944-8244
- Appears in Collections:
- Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- SuFEx in Metal−Organic Frameworks Versatile Postsynthetic.pdfDownload
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