SuFEx in Metal-Organic Frameworks: Versatile Postsynthetic Modification Tool

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Title
SuFEx in Metal-Organic Frameworks: Versatile Postsynthetic Modification Tool
Author(s)
Seungjae Park; Hayoung Song; Nakeun Ko; Kim, C; Kimoon Kim; Eunsung Lee
Publication Date
2018-10
Journal
ACS APPLIED MATERIALS & INTERFACES, v.10, no.40, pp.33785 - 33789
Publisher
AMER CHEMICAL SOC
Abstract
A new type of click reaction, sulfur(VI) fluoride exchange (SuFEx), has been utilized to prepare five postsynthetically modified UiO-67 series metal-organic frameworks (MOFs). The postsynthetic modification (PSM) via SuFEx can be achieved selectively for the sulfonyl fluoride (R-SO2F) without degrading the MOF structure as confirmed by X-ray crystallographic analysis. The present SuFEx method provides a straightforward tool for introducing new functionality inside MOFs. Introduction of an imidazolium group into the MOF afforded a heterogeneous catalyst for the benzoin condensation reaction. © 2018 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/5778
ISSN
1944-8244
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > Journal Papers (저널논문)
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