Cobalt-Catalyzed C-F Bond Borylation of Aryl Fluorides

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Title
Cobalt-Catalyzed C-F Bond Borylation of Aryl Fluorides
Author(s)
Soobin Lim; Dalnim Song; Seungwon Jeon; Youngsuk Kim; Hyunseok Kim; Sanghee Lee; Hyungdo Cho; Byung Chul Lee; Sang Eun Kim; Kimoon Kim; Eunsung Lee
Publication Date
2018-11
Journal
ORGANIC LETTERS, v.20, no.22, pp.7249 - 7252
Publisher
AMER CHEMICAL SOC
Abstract
A mild and practical cobalt-catalyzed defluoroborylation of fluoroarenes is presented for the first time. The method permits straightforward functionalization of fluoroarenes, with high selectivity for borylation of C-F over C-H bonds, and a tolerance for aerobic conditions. Furthermore, two-step 18F-fluorination was achieved for expanding the scope of 18F-positron emission tomography probes. c. 2018 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/5417
ISSN
1523-7060
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > Journal Papers (저널논문)
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