Facile C–H arylation using catalytically active terminal sulfurs of 2 dimensional molybdenum disulfide

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Title
Facile C–H arylation using catalytically active terminal sulfurs of 2 dimensional molybdenum disulfide
Author(s)
Eunhee Hwang; Sae Mi Lee; Sora Bak; Hee Min Hwang; Hyunjung Kim; Hyoyoung Lee
Publication Date
2018-10
Journal
TETRAHEDRON LETTERS, v.59, no.44, pp.3969 - 3973
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Abstract
The first methodology of C–H arylation of heteroarene via 2D transition metal dichalcogenides that have catalytically active edge functional groups was described. The terminal sulfur groups could effectively catalyze a formation of an azo-linked intermediate with aryl diazonium salts, leading to produce heteroarenes with good yields. This novel methodology using bulk 2D transition metal dichalcogenides that have catalytically active edge functional groups can apply for various reactions to achieve C–C bond formation in the fields of heterogeneous catalysis that is easily separable, highly reusable, and inexpensive method. © 2018 Elsevier Lt
URI
https://pr.ibs.re.kr/handle/8788114/5120
ISSN
0040-4039
Appears in Collections:
Center for Integrated Nanostructure Physics(나노구조물리 연구단) > Journal Papers (저널논문)
Files in This Item:
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