An air-stable N-heterocyclic carbene iminoxyl borate radical zwitterion

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Title
An air-stable N-heterocyclic carbene iminoxyl borate radical zwitterion
Author(s)
Youngsuk Kim; Lee E.
Publication Date
2018-06
Journal
CHEMICAL COMMUNICATIONS, v.54, no.50, pp.6824 - 6827
Publisher
ROYAL SOC CHEMISTRY
Abstract
A remarkably stable radical zwitterion derived from N-heterocyclic carbene nitric oxide and B(C6F5)3 is reported. The presented radical was generated by steric and electronic protection of the nitric oxide moiety using B(C6F5)3, which secured its stability toward air and moisture. An analogous yet less stable radical derived from C(C6H5)3 + is also synthesized and characterized. © 2018 The Royal Society of Chemistry
URI
https://pr.ibs.re.kr/handle/8788114/4976
ISSN
1359-7345
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > Journal Papers (저널논문)
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