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나노 구조 물리 연구단
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Quasi-High-Pressure Effects in Transition-Metal-Rich Dichalcogenide, Hf3Te2

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Title
Quasi-High-Pressure Effects in Transition-Metal-Rich Dichalcogenide, Hf3Te2
Author(s)
Ho Sung Yu; Byungki Ryu; Soohyung Park; Jongho Park; Yeonjin Yi; Kyu Hyoung Lee; Kimoon Lee; Sung Wng Kim
Publication Date
2017-11
Journal
Journal of Physical Chemistry C, v.121, no.45, pp.25541 - 25546
Publisher
AMER CHEMICAL SOC
Abstract
High pressure offers an intriguing avenue for the change in physical and chemical properties of condensed matters such as superconductivity, structural phase transition, and catalytic activity. However, it is hard to achieve the high-pressure phases of elements and compounds in an ambient condition by chemical pressure due to the limitation in bonding length variation. Here, we report the quasi-high-pressure state of Hf cuboid confined between two-dimensional chalcogen layers in transition-metal-rich dichalcogenide of Hf3Te2, exhibiting the enhanced degree of localization and chemical potential for valence electrons compared to ambient Hf elements. The structural analysis reveals that Hf metals in Hf3Te2 form a local cuboid structure, in which the coordination for central Hf is identical to that of high-pressure body-centered-cubic Hf phase. Density functional theory calculations verify that the compressed cuboid in Hf3Te2 has a key role for an abnormal heat capacity beyond Dulong Petit limit and reduced work function, resulting from the intrinsic pressure induced s-d transfer in covalent electrons between Hf Hf bonding. This transition-metal-rich dichalcogenide can guide a route to realize a high-pressure element under ambient condition and offer an opportunity to explore a new layered two-dimensional material. © 2017 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/4042
ISSN
1932-7447
Appears in Collections:
Center for Integrated Nanostructure Physics(나노구조물리 연구단) > Journal Papers (저널논문)
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