Ruthenium-Catalyzed Urea Synthesis Using Methanol as the C1 Source

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Title
Ruthenium-Catalyzed Urea Synthesis Using Methanol as the C1 Source
Author(s)
Seung Hyo Kim; Soon Hyeok Hong
Publication Date
2016-01
Journal
ORGANIC LETTERS, v.18, no.2, pp.212 - 215
Publisher
AMER CHEMICAL SOC
Abstract
An unprecedented protocol for urea synthesis directly from methanol and amine was accomplished. The reaction is highly atom-economical, producing hydrogen as the sole byproduct. Commercially available ruthenium pincer complexes were used as catalysts. In addition, no additive, such as a base, oxidant, or hydrogen acceptor, was required. Furthermore, unsymmetrical urea derivatives were successfully obtained via a one-pot, two-step reaction. © 2015 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/3317
ISSN
1523-7060
Appears in Collections:
Center for Nanoparticle Research(나노입자 연구단) > Journal Papers (저널논문)
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