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복잡계 자기조립 연구단
복잡계 자기조립 연구단
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Activation of C-F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexes

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Title
Activation of C-F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexes
Author(s)
Youngsuk Kim; Eunsung Lee
Publication Date
2016-09
Journal
CHEMICAL COMMUNICATIONS, v.52, no.72, pp.10922 - 10925
Publisher
ROYAL SOC CHEMISTRY
Abstract
IPr (1a) reacts with octafluorotoluene by an unexpected sequential substitution of fluorides in two separate rings. The resulting tetrasubstituted imidazolium salt was isolated and elaborated into Ag(i) and Au(i) complexes with a novel abnormal NHC ligand. Both IPr (1a) and IMes (1b) were also found to be moderately reactive by nucleophilic substitution of the aromatic C-F bond in a weakly-activated fluoroarene, 1-fluoro-4-trifluoromethylbenzene (5). © The Royal Society of Chemistry 2016
URI
https://pr.ibs.re.kr/handle/8788114/3009
ISSN
1359-7345
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > Journal Papers (저널논문)
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(20160817)Activation of C-F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexes.pdfDownload

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