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다차원 탄소재료 연구단
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A cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent

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Title
A cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent
Author(s)
Zachary R. McCarty; Dominika N. Lastovickova; Christopher W. Bielawski
Publication Date
2016-04
Journal
CHEMICAL COMMUNICATIONS, v.52, no.31, pp.5447 - 5450
Publisher
ROYAL SOC CHEMISTRY
Abstract
The synthesis and study of a cyclic (alkyl)(amido) carbene is described. The carbene was found to undergo C-H insertion at low temperatures, formed cyclopropenes upon exposure to alkynes, and facilitated desulfurization reactions. Spectroscopic studies revealed that the carbene is strongly pi-accepting but retains a complimentary degree of sigma-donating properties. ©The Royal Society of Chemistry 2016
URI
https://pr.ibs.re.kr/handle/8788114/2709
ISSN
1359-7345
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
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