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A cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent

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dc.contributor.authorZachary R. McCarty-
dc.contributor.authorDominika N. Lastovickova-
dc.contributor.authorChristopher W. Bielawski-
dc.date.available2016-07-21T08:49:59Z-
dc.date.created2016-05-17-
dc.date.issued2016-04-
dc.identifier.issn1359-7345-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/2709-
dc.description.abstractThe synthesis and study of a cyclic (alkyl)(amido) carbene is described. The carbene was found to undergo C-H insertion at low temperatures, formed cyclopropenes upon exposure to alkynes, and facilitated desulfurization reactions. Spectroscopic studies revealed that the carbene is strongly pi-accepting but retains a complimentary degree of sigma-donating properties. ©The Royal Society of Chemistry 2016-
dc.description.uri1-
dc.language영어-
dc.publisherROYAL SOC CHEMISTRY-
dc.titleA cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000374033700022-
dc.identifier.scopusid2-s2.0-84964467022-
dc.identifier.rimsid55398ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorDominika N. Lastovickova-
dc.contributor.affiliatedAuthorChristopher W. Bielawski-
dc.identifier.doi10.1039/c6cc01376g-
dc.identifier.bibliographicCitationCHEMICAL COMMUNICATIONS, v.52, no.31, pp.5447 - 5450-
dc.citation.titleCHEMICAL COMMUNICATIONS-
dc.citation.volume52-
dc.citation.number31-
dc.citation.startPage5447-
dc.citation.endPage5450-
dc.date.scptcdate2018-10-01-
dc.description.wostc8-
dc.description.scptc8-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusN-HETEROCYCLIC CARBENES-
dc.subject.keywordPlusALKYL AMINO CARBENES-
dc.subject.keywordPlusLIGAND PROPERTIES-
dc.subject.keywordPlusDONOR PROPERTIES-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusBACKBONE-
dc.subject.keywordPlusN,N&apos-
dc.subject.keywordPlus-DIAMIDOCARBENE-
dc.subject.keywordPlusPARAMETERS-
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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