A cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zachary R. McCarty | - |
dc.contributor.author | Dominika N. Lastovickova | - |
dc.contributor.author | Christopher W. Bielawski | - |
dc.date.available | 2016-07-21T08:49:59Z | - |
dc.date.created | 2016-05-17 | - |
dc.date.issued | 2016-04 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/2709 | - |
dc.description.abstract | The synthesis and study of a cyclic (alkyl)(amido) carbene is described. The carbene was found to undergo C-H insertion at low temperatures, formed cyclopropenes upon exposure to alkynes, and facilitated desulfurization reactions. Spectroscopic studies revealed that the carbene is strongly pi-accepting but retains a complimentary degree of sigma-donating properties. ©The Royal Society of Chemistry 2016 | - |
dc.description.uri | 1 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000374033700022 | - |
dc.identifier.scopusid | 2-s2.0-84964467022 | - |
dc.identifier.rimsid | 55398 | ko |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Dominika N. Lastovickova | - |
dc.contributor.affiliatedAuthor | Christopher W. Bielawski | - |
dc.identifier.doi | 10.1039/c6cc01376g | - |
dc.identifier.bibliographicCitation | CHEMICAL COMMUNICATIONS, v.52, no.31, pp.5447 - 5450 | - |
dc.citation.title | CHEMICAL COMMUNICATIONS | - |
dc.citation.volume | 52 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 5447 | - |
dc.citation.endPage | 5450 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 8 | - |
dc.description.scptc | 8 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENES | - |
dc.subject.keywordPlus | ALKYL AMINO CARBENES | - |
dc.subject.keywordPlus | LIGAND PROPERTIES | - |
dc.subject.keywordPlus | DONOR PROPERTIES | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | REACTIVITY | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | BACKBONE | - |
dc.subject.keywordPlus | N,N&apos | - |
dc.subject.keywordPlus | -DIAMIDOCARBENE | - |
dc.subject.keywordPlus | PARAMETERS | - |