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N-Heterocyclic Carbene Nitric Oxide Radicals

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Title
N-Heterocyclic Carbene Nitric Oxide Radicals
Author(s)
Park J.; Song H.; Kim Y.; Bit Eun; Yonghwi Kim; Dae Young Bae; Sungho Park; Young Min Rhee; Won Jong Kim; Kimoon Kim; Eunsung Lee
Subject
Alkyl Amino Carbenes, ; Crystalline Carbene, ; Nitrous-oxide, ; Donors, ; Cation, ; Chemistry, ; Catalysts, ; Silylene, ; Ligands, ; Biology
Publication Date
2015-04
Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.137, no.14, pp.4642 - 4645
Publisher
AMER CHEMICAL SOC
Abstract
N-Heterocyclic carbene-stabilized nitric oxide radicals were prepared by direct addition of nitric oxide to two N-heterocyclic carbenes in solution phase. The compounds were fully characterized by X-ray crystallography and EPR. The nitric oxide moiety in the solid compounds obtained can be thermally transferred to another N-heterocyclic carbene, suggesting potential applications to NO delivery. © 2015 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/1628
DOI
10.1021/jacs.5b01976
ISSN
0002-7863
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > 1. Journal Papers (저널논문)
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