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Dy(III) Single-Ion Magnet Showing Extreme Sensitivity to (De)hydration

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Title
Dy(III) Single-Ion Magnet Showing Extreme Sensitivity to (De)hydration
Author(s)
Ren, Min; Pinkowicz, Dawid; Minyoung Yoon; Ki Moon Kim; Zheng, Li-Min; Breedlove, Brian K.; Yamashita, Masahiro
Publication Date
2013-08
Journal
INORGANIC CHEMISTRY, v.52, no.15, pp.8342 - 8348
Publisher
AMER CHEMICAL SOC
Abstract
A new mononuclear dysprosium(III)-cucurbit[6]uril com- plex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature- dependent regimes.
URI
https://pr.ibs.re.kr/handle/8788114/1285
DOI
10.1021/ic400430q
ISSN
0020-1669
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
2013-08-05-Inorganic Chemistry-Dy(III) Single-Ion.pdfDownload

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