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Inverse Vulcanization of Elemental Sulfur to Prepare Polymeric Electrode Materials for Li–S Batteries Highly Cited Paper

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Title
Inverse Vulcanization of Elemental Sulfur to Prepare Polymeric Electrode Materials for Li–S Batteries
Author(s)
Adam G.Simmonds; Jared J.Griebel; Jungjin Park; Kwi Ryong Kim; Woo Jin Chung; Vladimir P. Oleshko; Jenny Kim; Eui Tae Kim; Richard S. Glass; Christopher L. Soles; Yung Eun Sung; Kookheon Char; Jeffrey Pyun
Publication Date
2014-02
Journal
ACS MACRO LETTERS, v.3, no.3, pp.229 - 232
Publisher
AMER CHEMICAL SOC
Abstract
Sulfur-rich copolymers based on poly(sulfurrandom- 1,3-diisopropenylbenzene) (poly(S-r-DIB)) were synthesized via inverse vulcanization to create cathode materials for lithium−sulfur battery applications. These materials exhibit enhanced capacity retention (1005 mAh/g at 100 cycles) and battery lifetimes over 500 cycles at a C/10 rate. These poly(Sr- DIB) copolymers represent a new class of polymeric electrode materials that exhibit one of the highest charge capacities reported, particularly after extended charge− discharge cycling in Li−S batteries.
URI
https://pr.ibs.re.kr/handle/8788114/1134
ISSN
2161-1653
Appears in Collections:
Center for Nanoparticle Research(나노입자 연구단) > Journal Papers (저널논문)
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