BROWSE

Related Scientist

CSC's photo.

CSC
복잡계 자기조립 연구단
more info

ITEM VIEW & DOWNLOAD

Construction of Stable Metal-Organic Framework Platforms Embedding N-Heterocyclic Carbene Metal Complexes for Selective Catalysis

Cited 0 time in webofscience Cited 0 time in scopus
111 Viewed 0 Downloaded
Title
Construction of Stable Metal-Organic Framework Platforms Embedding N-Heterocyclic Carbene Metal Complexes for Selective Catalysis
Author(s)
Hyunyong Kim; Kim, Hyunseok; Kimoon Kim; Eunsung Lee
Publication Date
2021-12-20
Journal
Inorganic Chemistry, v.60, no.24, pp.18687 - 18697
Publisher
American Chemical Society
Abstract
© 2021 American Chemical Society.We report a bottom-up approach to immobilize catalysts into MOFs, including copper halides and gold chloride in a predictable manner. Interestingly, the structures of MOFs bearing NHC metal complexes maintained a similar 4-fold interpenetrated cube. They exhibited exceptionally high porosity despite the interpenetrated structure and showed good stability in various solvents. Moreover, these MOFs possess high size activity depending on the size of the substrates in various reactions, compared to homogeneous catalysis. Also, the high catalytic activity of MOFs can be preserved 4 times without significant loss of crystallinity. Incorporation of the various metal complexes into MOFs allows for the preparation of functional MOFs for practical applications.
URI
https://pr.ibs.re.kr/handle/8788114/10997
DOI
10.1021/acs.inorgchem.1c02070
ISSN
0020-1669
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse