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Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis

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Title
Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis
Author(s)
Seongho Jin; Jinwoo Kim; Dongwook Kim; Jung-Woo Park; Sukbok Chang
Subject
FUNCTIONALIZATION, ; CARBON, ; BONDS, ; ACYLOXYLATION, ; ACTIVATION, ; ALCOHOL, ; WATER
Publication Date
2021-06-04
Journal
ACS CATALYSIS, v.11, no.11, pp.6590 - 6595
Publisher
American Chemical Society
Abstract
© 2021 American Chemical Society.Herein, we describe the development of a Rh-catalyzed C-H acyloxylation under mild electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was found to enable the product-releasing C-O bond-forming reductive elimination process. An accumulation of carboxylate near the electrode surface was rationalized to further induce the desired C-O bond formation, allowing an ambient catalytic C-H oxygenation using stoichiometric amounts of readily accessible carboxylic acid coupling partners.
URI
https://pr.ibs.re.kr/handle/8788114/9934
DOI
10.1021/acscatal.1c01670
ISSN
2155-5435
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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