IBS Publications Repository: Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis

DC Field	Value	Language
dc.contributor.author	Seongho Jin	-
dc.contributor.author	Jinwoo Kim	-
dc.contributor.author	Dongwook Kim	-
dc.contributor.author	Jung-Woo Park	-
dc.contributor.author	Sukbok Chang	-
dc.date.accessioned	2021-07-12T06:30:06Z	-
dc.date.accessioned	2021-07-12T06:30:06Z	-
dc.date.available	2021-07-12T06:30:06Z	-
dc.date.available	2021-07-12T06:30:06Z	-
dc.date.created	2021-07-07	-
dc.date.issued	2021-06-04	-
dc.identifier.issn	2155-5435	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/9934	-
dc.description.abstract	© 2021 American Chemical Society.Herein, we describe the development of a Rh-catalyzed C-H acyloxylation under mild electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was found to enable the product-releasing C-O bond-forming reductive elimination process. An accumulation of carboxylate near the electrode surface was rationalized to further induce the desired C-O bond formation, allowing an ambient catalytic C-H oxygenation using stoichiometric amounts of readily accessible carboxylic acid coupling partners.	-
dc.language	영어	-
dc.publisher	American Chemical Society	-
dc.title	Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000661125100025	-
dc.identifier.scopusid	2-s2.0-85108194877	-
dc.identifier.rimsid	75930	-
dc.contributor.affiliatedAuthor	Seongho Jin	-
dc.contributor.affiliatedAuthor	Jinwoo Kim	-
dc.contributor.affiliatedAuthor	Dongwook Kim	-
dc.contributor.affiliatedAuthor	Jung-Woo Park	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.identifier.doi	10.1021/acscatal.1c01670	-
dc.identifier.bibliographicCitation	ACS CATALYSIS, v.11, no.11, pp.6590 - 6595	-
dc.relation.isPartOf	ACS CATALYSIS	-
dc.citation.title	ACS CATALYSIS	-
dc.citation.volume	11	-
dc.citation.number	11	-
dc.citation.startPage	6590	-
dc.citation.endPage	6595	-
dc.type.docType	Article	-
dc.description.journalClass	1	-
dc.description.journalClass	1	-
dc.description.isOpenAccess	N	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.relation.journalResearchArea	Chemistry	-
dc.relation.journalWebOfScienceCategory	Chemistry, Physical	-
dc.subject.keywordPlus	FUNCTIONALIZATION	-
dc.subject.keywordPlus	CARBON	-
dc.subject.keywordPlus	BONDS	-
dc.subject.keywordPlus	ACYLOXYLATION	-
dc.subject.keywordPlus	ACTIVATION	-
dc.subject.keywordPlus	ALCOHOL	-
dc.subject.keywordPlus	WATER	-
dc.subject.keywordAuthor	C-H activation	-
dc.subject.keywordAuthor	electrochemistry	-
dc.subject.keywordAuthor	C-O bond formation	-
dc.subject.keywordAuthor	reductive elimination	-
dc.subject.keywordAuthor	high-valent pathway	-