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분자활성 촉매반응 연구단
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Electrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis

DC Field Value Language
dc.contributor.authorSeongho Jin-
dc.contributor.authorJinwoo Kim-
dc.contributor.authorDongwook Kim-
dc.contributor.authorJung-Woo Park-
dc.contributor.authorSukbok Chang-
dc.date.accessioned2021-07-12T06:30:06Z-
dc.date.accessioned2021-07-12T06:30:06Z-
dc.date.available2021-07-12T06:30:06Z-
dc.date.available2021-07-12T06:30:06Z-
dc.date.created2021-07-07-
dc.date.issued2021-06-
dc.identifier.issn2155-5435-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/9934-
dc.description.abstract© 2021 American Chemical Society.Herein, we describe the development of a Rh-catalyzed C-H acyloxylation under mild electrolytic conditions. Anodic oxidation of a key rhodacyclic carboxylate intermediate was found to enable the product-releasing C-O bond-forming reductive elimination process. An accumulation of carboxylate near the electrode surface was rationalized to further induce the desired C-O bond formation, allowing an ambient catalytic C-H oxygenation using stoichiometric amounts of readily accessible carboxylic acid coupling partners.-
dc.description.uri1-
dc.language영어-
dc.publisherAmerican Chemical Society-
dc.titleElectrolytic C-H Oxygenation via Oxidatively Induced Reductive Elimination in Rh Catalysis-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000661125100025-
dc.identifier.scopusid2-s2.0-85108194877-
dc.identifier.rimsid75930-
dc.contributor.affiliatedAuthorSeongho Jin-
dc.contributor.affiliatedAuthorJinwoo Kim-
dc.contributor.affiliatedAuthorDongwook Kim-
dc.contributor.affiliatedAuthorJung-Woo Park-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1021/acscatal.1c01670-
dc.identifier.bibliographicCitationACS CATALYSIS, v.11, no.11, pp.6590 - 6595-
dc.citation.titleACS CATALYSIS-
dc.citation.volume11-
dc.citation.number11-
dc.citation.startPage6590-
dc.citation.endPage6595-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.subject.keywordPlusFUNCTIONALIZATION-
dc.subject.keywordPlusCARBON-
dc.subject.keywordPlusBONDS-
dc.subject.keywordPlusACYLOXYLATION-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusALCOHOL-
dc.subject.keywordPlusWATER-
dc.subject.keywordAuthorC-H activation-
dc.subject.keywordAuthorelectrochemistry-
dc.subject.keywordAuthorC-O bond formation-
dc.subject.keywordAuthorreductive elimination-
dc.subject.keywordAuthorhigh-valent pathway-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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