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Poly(carbyne)s via reductive C1 polymerization

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Title
Poly(carbyne)s via reductive C1 polymerization
Author(s)
Collin R Cahoon; Karel Goossens; Christopher W Bielawski
Publication Date
2021-01
Journal
Polymer International, v.70, no.1, pp.34 - 40
Publisher
John Wiley & Sons Inc.
Abstract
C1 polymerizations enable the synthesis of densely functionalized, persubstituted polymers that are challenging to access using conventional methods. One class of C1 polymers are the poly(carbyne)s, which are unique in that they can adopt branched or linear structures, or combinations thereof. Herein, we report the synthesis of new poly(carbyne)s, including those that feature side chains with carbonyl-containing functional groups. The polymers were obtained by exposing solutions of monomers outfitted with trihalomethyl or trimethyl orthoformate groups to metallic lithium, and reaction performance was improved when electron transfer agents (e.g. naphthalene) were included. The mechanisms of the polymerizations were also deconvoluted and found to depend on the monomer employed.
URI
https://pr.ibs.re.kr/handle/8788114/9011
DOI
10.1002/pi.6115
ISSN
0959-8103
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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