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Scope and mechanism of nitrile dihydroboration mediated by a beta-diketiminate manganese hydride catalyst

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Title
Scope and mechanism of nitrile dihydroboration mediated by a beta-diketiminate manganese hydride catalyst
Author(s)
Thao T. Nguyen; Jun-Hyeong Kim,; Suyeon Kim; Changjin Oh; Marco Flores; Thomas L. Groy; Mu-Hyun Baik; Ryan J. Trovitch
Subject
DOUBLE HYDROBORATION, ; COMPLEX, ; COBALT, ; IRON, ; SINGLE, ; BOND
Publication Date
2020-04
Journal
CHEMICAL COMMUNICATIONS, v.56, no.28, pp.3959 - 3962
Publisher
ROYAL SOC CHEMISTRY
Abstract
The manganese hydride dimer, [(2,6-iPr(2)PhBDI)Mn(mu-H)](2), was found to mediate nitrile dihydroboration, rendering it the first manganese catalyst for this transformation. Stoichiometric experiments revealed that benzonitrile insertion affords [(2,6-iPr(2)PBDI)Mn(mu-NCHC6H5)](2) en route to N,N-diborylamine formation. Density functional theory calculations reveal the precise mechanism and demonstrate that catalysis is promoted by monomeric species. ©The Royal Society of Chemistry 2020
URI
https://pr.ibs.re.kr/handle/8788114/8654
DOI
10.1039/c9cc09921b
ISSN
1359-7345
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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