IBS Publications Repository: Scope and mechanism of nitrile dihydroboration mediated by a beta-diketiminate manganese hydride catalyst

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Scope and mechanism of nitrile dihydroboration mediated by a beta-diketiminate manganese hydride catalyst

DC Field	Value	Language
dc.contributor.author	Thao T. Nguyen	-
dc.contributor.author	Jun-Hyeong Kim,	-
dc.contributor.author	Suyeon Kim	-
dc.contributor.author	Changjin Oh	-
dc.contributor.author	Marco Flores	-
dc.contributor.author	Thomas L. Groy	-
dc.contributor.author	Mu-Hyun Baik	-
dc.contributor.author	Ryan J. Trovitch	-
dc.date.accessioned	2020-12-22T06:35:08Z	-
dc.date.accessioned	2020-12-22T06:35:08Z	-
dc.date.available	2020-12-22T06:35:08Z	-
dc.date.available	2020-12-22T06:35:08Z	-
dc.date.created	2020-06-29	-
dc.date.issued	2020-04	-
dc.identifier.issn	1359-7345	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/8654	-
dc.description.abstract	The manganese hydride dimer, [(2,6-iPr(2)PhBDI)Mn(mu-H)](2), was found to mediate nitrile dihydroboration, rendering it the first manganese catalyst for this transformation. Stoichiometric experiments revealed that benzonitrile insertion affords [(2,6-iPr(2)PBDI)Mn(mu-NCHC6H5)](2) en route to N,N-diborylamine formation. Density functional theory calculations reveal the precise mechanism and demonstrate that catalysis is promoted by monomeric species. ©The Royal Society of Chemistry 2020	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	ROYAL SOC CHEMISTRY	-
dc.subject	DOUBLE HYDROBORATION	-
dc.subject	COMPLEX	-
dc.subject	COBALT	-
dc.subject	IRON	-
dc.subject	SINGLE	-
dc.subject	BOND	-
dc.title	Scope and mechanism of nitrile dihydroboration mediated by a beta-diketiminate manganese hydride catalyst	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000524565800004	-
dc.identifier.scopusid	2-s2.0-85083002905	-
dc.identifier.rimsid	72142	-
dc.contributor.affiliatedAuthor	Jun-Hyeong Kim,	-
dc.contributor.affiliatedAuthor	Suyeon Kim	-
dc.contributor.affiliatedAuthor	Changjin Oh	-
dc.contributor.affiliatedAuthor	Mu-Hyun Baik	-
dc.identifier.doi	10.1039/c9cc09921b	-
dc.identifier.bibliographicCitation	CHEMICAL COMMUNICATIONS, v.56, no.28, pp.3959 - 3962	-
dc.citation.title	CHEMICAL COMMUNICATIONS	-
dc.citation.volume	56	-
dc.citation.number	28	-
dc.citation.startPage	3959	-
dc.citation.endPage	3962	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordPlus	DOUBLE HYDROBORATION	-
dc.subject.keywordPlus	COMPLEX	-
dc.subject.keywordPlus	COBALT	-
dc.subject.keywordPlus	IRON	-
dc.subject.keywordPlus	SINGLE	-
dc.subject.keywordPlus	BOND	-