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분자활성 촉매반응 연구단
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Scope and mechanism of nitrile dihydroboration mediated by a beta-diketiminate manganese hydride catalyst

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dc.contributor.authorThao T. Nguyen-
dc.contributor.authorJun-Hyeong Kim,-
dc.contributor.authorSuyeon Kim-
dc.contributor.authorChangjin Oh-
dc.contributor.authorMarco Flores-
dc.contributor.authorThomas L. Groy-
dc.contributor.authorMu-Hyun Baik-
dc.contributor.authorRyan J. Trovitch-
dc.date.accessioned2020-12-22T06:35:08Z-
dc.date.accessioned2020-12-22T06:35:08Z-
dc.date.available2020-12-22T06:35:08Z-
dc.date.available2020-12-22T06:35:08Z-
dc.date.created2020-06-29-
dc.date.issued2020-04-
dc.identifier.issn1359-7345-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/8654-
dc.description.abstractThe manganese hydride dimer, [(2,6-iPr(2)PhBDI)Mn(mu-H)](2), was found to mediate nitrile dihydroboration, rendering it the first manganese catalyst for this transformation. Stoichiometric experiments revealed that benzonitrile insertion affords [(2,6-iPr(2)PBDI)Mn(mu-NCHC6H5)](2) en route to N,N-diborylamine formation. Density functional theory calculations reveal the precise mechanism and demonstrate that catalysis is promoted by monomeric species. ©The Royal Society of Chemistry 2020-
dc.description.uri1-
dc.language영어-
dc.publisherROYAL SOC CHEMISTRY-
dc.subjectDOUBLE HYDROBORATION-
dc.subjectCOMPLEX-
dc.subjectCOBALT-
dc.subjectIRON-
dc.subjectSINGLE-
dc.subjectBOND-
dc.titleScope and mechanism of nitrile dihydroboration mediated by a beta-diketiminate manganese hydride catalyst-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000524565800004-
dc.identifier.scopusid2-s2.0-85083002905-
dc.identifier.rimsid72142-
dc.contributor.affiliatedAuthorJun-Hyeong Kim,-
dc.contributor.affiliatedAuthorSuyeon Kim-
dc.contributor.affiliatedAuthorChangjin Oh-
dc.contributor.affiliatedAuthorMu-Hyun Baik-
dc.identifier.doi10.1039/c9cc09921b-
dc.identifier.bibliographicCitationCHEMICAL COMMUNICATIONS, v.56, no.28, pp.3959 - 3962-
dc.citation.titleCHEMICAL COMMUNICATIONS-
dc.citation.volume56-
dc.citation.number28-
dc.citation.startPage3959-
dc.citation.endPage3962-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusDOUBLE HYDROBORATION-
dc.subject.keywordPlusCOMPLEX-
dc.subject.keywordPlusCOBALT-
dc.subject.keywordPlusIRON-
dc.subject.keywordPlusSINGLE-
dc.subject.keywordPlusBOND-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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