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나노물질 및 화학반응 연구단
나노물질 및 화학반응 연구단
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A highly Lewis-acidic Pd(iv) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions

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Title
A highly Lewis-acidic Pd(iv) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions
Author(s)
Mijong Kim; Suyeon Lee; Kim K.; Shin D.; Hyunwoo Kim; Hyunjoon Song
Publication Date
2014-12
Journal
CHEMICAL COMMUNICATIONS, v.50, no.95, pp.14938 - 14941
Publisher
ROYAL SOC CHEMISTRY
Abstract
The Pd(IV) species, known to be critical intermediates in homogeneous catalysis, were successfully generated on the surface of Pd nanocatalysts via oxidation with iodobenzene dichloride (PhICl2) or N-chlorosuccinimide (NCS). In particular, the Pd@SiO2 yolk–shell nanocatalyst activated by PhICl2 showed high reactivity and superior stability to the other Pd-based catalysts for hydroalkoxylation reactions even at 25 8C.
URI
https://pr.ibs.re.kr/handle/8788114/852
ISSN
1359-7345
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > Journal Papers (저널논문)
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