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IBS Publications RepositoryCenter for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단)1. Journal Papers (저널논문)
A highly Lewis-acidic Pd(iv) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions
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- Title
- A highly Lewis-acidic Pd(iv) surface on Pd@SiO2 nanocatalysts for hydroalkoxylation reactions
- Author(s)
- Mijong Kim; Suyeon Lee; Kim K.; Shin D.; Hyunwoo Kim; Hyunjoon Song
- Publication Date
- 2014-12
- Journal
- CHEMICAL COMMUNICATIONS, v.50, no.95, pp.14938 - 14941
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- The Pd(IV) species, known to be critical intermediates in homogeneous catalysis, were successfully generated on the surface of Pd nanocatalysts via oxidation with iodobenzene dichloride (PhICl2) or N-chlorosuccinimide (NCS). In particular, the Pd@SiO2 yolk–shell nanocatalyst activated by PhICl2 showed high reactivity and superior stability to the other Pd-based catalysts for hydroalkoxylation reactions even at 25 8C.
- ISSN
- 1359-7345
- Appears in Collections:
- Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- 112ChemCommun1.pdfDownload
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