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Indirect Interactions between Raman Probes Encapsulated within Cucurbit[7]urils and Gold Nanorods to Enhance Long-term Stability and Signal

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Title
Indirect Interactions between Raman Probes Encapsulated within Cucurbit[7]urils and Gold Nanorods to Enhance Long-term Stability and Signal
Author(s)
Seo, MJ; Kangkyun Baek; Ha, JW
Publication Date
2019-09
Journal
ANALYTICAL SCIENCES, v.35, no.9, pp.1009 - 1013
Publisher
JAPAN SOC ANALYTICAL CHEMISTRY
Abstract
Surface-enhanced Raman scattering (SERS) is a powerful technique that enhances Raman signals by adsorbing probe molecules on rough metal surfaces. However, SERS is limited because target molecules must strongly interact with metal to enhance a stable Raman signal. In this study, to improve long-term SERS stability, we use cucurbit[7]urils (CB[7]) as bridge molecules and sample containers to probe Rhodamine 6G (R6G) molecules. We observed interactions between gold nanorods (AuNRs) and CB[7] via aggregate formation, which enhanced the Raman signal and improved long-term R6G probe stability by up to 20 days when encapsulated within CB[7] during SERS analysis. C.2019 The Japan Society for Analytical Chemistry.
URI
https://pr.ibs.re.kr/handle/8788114/6425
ISSN
0910-6340
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > Journal Papers (저널논문)
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