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Comparison of the Reactivities and Selectivities of Group9 [Cp*M-III] Catalysts in C-H Functionalization Reactions

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Title
Comparison of the Reactivities and Selectivities of Group9 [Cp*M-III] Catalysts in C-H Functionalization Reactions
Author(s)
Juhyeon Park; Sukbok Chang
Publication Date
2018-05
Journal
CHEMISTRY-AN ASIAN JOURNAL, v.13, no.9, pp.1089 - 1102
Publisher
WILEY-V C H VERLAG GMBH
Abstract
Pentamethylcyclopentadienyl (Cp*)-based Group9 metal (Co, Rh, or Ir) catalysts have emerged as powerful tools for C-H functionalization reactions. Whilst a diverse range of organic transformations have been developed by using [Cp*M-III] catalysts, they have often exhibited orthogonal reactivities and varied selectivities that depended on the choice of the central metal atom. An understanding of the physicochemical properties of the metals, as well as of their reaction mechanisms, has led to significant expansion of the synthetic scope of C-H functionalization reactions. This Focus Review summarizes and discusses the comparative catalytic reactivities and selectivities of the [Cp*M-III] catalysts, with an emphasis on metal-dependent pathway-switching by considering the mechanistic rationale ⓒ 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/5925
ISSN
1861-4728
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
C_Comparison of the Reactivities_asia.201800204.pdfDownload

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