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분자활성촉매반응연구단
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Comparison of the Reactivities and Selectivities of Group9 [Cp*M-III] Catalysts in C-H Functionalization Reactions

DC Field Value Language
dc.contributor.authorJuhyeon Park-
dc.contributor.authorSukbok Chang-
dc.date.available2019-07-19T05:41:09Z-
dc.date.created2019-06-19-
dc.date.issued2018-05-
dc.identifier.issn1861-4728-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/5925-
dc.description.abstractPentamethylcyclopentadienyl (Cp*)-based Group9 metal (Co, Rh, or Ir) catalysts have emerged as powerful tools for C-H functionalization reactions. Whilst a diverse range of organic transformations have been developed by using [Cp*M-III] catalysts, they have often exhibited orthogonal reactivities and varied selectivities that depended on the choice of the central metal atom. An understanding of the physicochemical properties of the metals, as well as of their reaction mechanisms, has led to significant expansion of the synthetic scope of C-H functionalization reactions. This Focus Review summarizes and discusses the comparative catalytic reactivities and selectivities of the [Cp*M-III] catalysts, with an emphasis on metal-dependent pathway-switching by considering the mechanistic rationale ⓒ 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.language영어-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectC-H functionalization-
dc.subjectcobalt-
dc.subjectiridium-
dc.subjectreaction mechanisms-
dc.subjectrhodium-
dc.titleComparison of the Reactivities and Selectivities of Group9 [Cp*M-III] Catalysts in C-H Functionalization Reactions-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000431625200002-
dc.identifier.scopusid2-s2.0-85044541868-
dc.identifier.rimsid68737-
dc.contributor.affiliatedAuthorJuhyeon Park-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1002/asia.201800204-
dc.identifier.bibliographicCitationCHEMISTRY-AN ASIAN JOURNAL, v.13, no.9, pp.1089 - 1102-
dc.relation.isPartOfCHEMISTRY-AN ASIAN JOURNAL-
dc.citation.titleCHEMISTRY-AN ASIAN JOURNAL-
dc.citation.volume13-
dc.citation.number9-
dc.citation.startPage1089-
dc.citation.endPage1102-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordPlusCARBON-CARBON BONDS-
dc.subject.keywordPlusINDOLE SYNTHESIS-
dc.subject.keywordPlusN BOND-
dc.subject.keywordPlusAMIDO TRANSFER-
dc.subject.keywordPlusBENZOIC-ACIDS-
dc.subject.keywordPlusACTIVATION-
dc.subject.keywordPlusRHODIUM-
dc.subject.keywordPlusAMIDATION-
dc.subject.keywordPlusALKYNES-
dc.subject.keywordPlusMILD-
dc.subject.keywordAuthorC-H functionalization-
dc.subject.keywordAuthorcobalt-
dc.subject.keywordAuthoriridium-
dc.subject.keywordAuthorreaction mechanisms-
dc.subject.keywordAuthorrhodium-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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