Influence of carbon doping concentration on photoelectrochemical activity of TiO2 nanotube arrays under water oxidation

Cited 0 time in webofscience Cited 0 time in scopus
21 Viewed 6 Downloaded
Title
Influence of carbon doping concentration on photoelectrochemical activity of TiO2 nanotube arrays under water oxidation
Author(s)
Eun Heui Gwag; Song Yi Moon; Indranil Mondal; Jeong Young Park
Publication Date
2019-02
Journal
Catalysis Science & Technology, v.9, no.3, pp.688 - 694
Publisher
ROYAL SOC CHEMISTRY
Abstract
The effect of dopants on photocatalytic activity has been extensively studied because of its potential for the smart design of more energy- and cost-efficient catalytic materials. Here, we investigated the quantitative effects of carbon dopants on TiO2 nanotube arrays for photoelectrochemical (PEC) water splitting. This was enabled by doping different concentrations of interstitial carbon into TiO2 nanotube arrays using thermal treatment with controlled exposure time to the carbon precursor (ethanol vapor). There was no change in the morphology of the nanotube arrays, but the dopant (or defect) levels that were introduced into the TiO2 band gap absorbed visible light (>425 nm) to overcome the relatively large band gap of the TiO2, which only reacts under UV light. We also examined interstitial carbon dopants that form oxygen vacancies, which can suppress the recombination of photogenerated charge carriers by temporarily trapping holes. Those two improvements increased the number of available charge carriers, resulting in enhanced PEC performance. The carbon doped TiO2 nanotube arrays fabricated under eight hours of ethanol exposure exhibited maximal efficiency and photocatalytic activity under simulated solar light. © 2019 The Royal Society of Chemistry
URI
https://pr.ibs.re.kr/handle/8788114/5710
ISSN
2044-4753
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > Journal Papers (저널논문)
Files in This Item:
Catal. Sci. Technol., 2019, 9, 688–694.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse