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다차원 탄소재료 연구단
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Metal-promoted C1 polymerizations

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Title
Metal-promoted C1 polymerizations
Author(s)
Collin R. Cahoon; Christopher W. Bielawski
Publication Date
2018-11
Journal
COORDINATION CHEMISTRY REVIEWS, v.374, no., pp.261 - 278
Publisher
ELSEVIER B.V
Abstract
C1 polymerizations provide a means to grow polymer chains one carbon atom at a time. Such methodology enables the synthesis of persubstituted polymers that are challenging to prepare using conventional C2 polymerizations, which typically utilize alkene-based monomers and thus grow polymer chains two carbons at a time. Persubstituted polymers feature higher densities of pendant functional groups and, as such, offer the potential to exhibit enhanced physical and/or chemical properties over their monosubstituted C2 polymer analogues. This review summarizes the various metals that have been used to promote C1 polymerizations in a catalytic or stoichiometric manner. Discussions are stratified according to the monomers used, which are formally carbenes or carbynes and typically employed as their respective ylides, isocyanides, diazo compounds, or geminal di- or trihalides. Emphasis is placed on the scope of the polymerization chemistry, underlying mechanisms, and outstanding opportunities in the field. © 2018 Elsevier B.V
URI
https://pr.ibs.re.kr/handle/8788114/5521
ISSN
0010-8545
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
Files in This Item:
15. 1-s2.0-S001085451830273X-main.pdfDownload

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