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분자활성 촉매반응 연구단
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Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides

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Title
Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides
Author(s)
Youngchan Kim; Ramesh B. Dateer; Sukbok Chang
Publication Date
2017-01
Journal
ORGANIC LETTERS, v.19, no.1, pp.190 - 193
Publisher
AMER CHEMICAL SOC
Abstract
We have developed a borane-catalyzed regio- and stereoselective hydrosilylation of internal ynamides for the first time. The scope of ynamide substrates and silane reactants was broad under mild reaction conditions, affording synthetically versatile beta-silyl (Z)-enamide products. The observed stereoselectivity was reasoned to be due to the beta-silicon effect on a postulated, ketene iminium intermediate © 2016 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/4821
ISSN
1523-7060
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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C_Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides.pdfDownload

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