Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Youngchan Kim | - |
dc.contributor.author | Ramesh B. Dateer | - |
dc.contributor.author | Sukbok Chang | - |
dc.date.available | 2018-07-18T02:09:15Z | - |
dc.date.created | 2018-03-16 | - |
dc.date.issued | 2017-01 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/4821 | - |
dc.description.abstract | We have developed a borane-catalyzed regio- and stereoselective hydrosilylation of internal ynamides for the first time. The scope of ynamide substrates and silane reactants was broad under mild reaction conditions, affording synthetically versatile beta-silyl (Z)-enamide products. The observed stereoselectivity was reasoned to be due to the beta-silicon effect on a postulated, ketene iminium intermediate © 2016 American Chemical Society | - |
dc.description.uri | 1 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000391781600049 | - |
dc.identifier.scopusid | 2-s2.0-85020593123 | - |
dc.identifier.rimsid | 62475 | ko |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Youngchan Kim | - |
dc.contributor.affiliatedAuthor | Ramesh B. Dateer | - |
dc.contributor.affiliatedAuthor | Sukbok Chang | - |
dc.identifier.doi | 10.1021/acs.orglett.6b03485 | - |
dc.identifier.bibliographicCitation | ORGANIC LETTERS, v.19, no.1, pp.190 - 193 | - |
dc.citation.title | ORGANIC LETTERS | - |
dc.citation.volume | 19 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 190 | - |
dc.citation.endPage | 193 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 8 | - |
dc.description.scptc | 8 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | TRISUBSTITUTED HOMOALLYLIC ALCOHOLS | - |
dc.subject.keywordPlus | CROSS-COUPLING REACTIONS | - |
dc.subject.keywordPlus | STEREOSELECTIVE HYDROSILYLATION | - |
dc.subject.keywordPlus | ALKYNE HYDROSILYLATION | - |
dc.subject.keywordPlus | TRANS-HYDROSILYLATION | - |
dc.subject.keywordPlus | ORGANIC-SYNTHESIS | - |
dc.subject.keywordPlus | TERMINAL ALKYNES | - |
dc.subject.keywordPlus | VINYL CATIONS | - |
dc.subject.keywordPlus | B(C6F5)(3)-CATALYZED HYDROSILYLATION | - |
dc.subject.keywordPlus | REGIOSELECTIVE HYDROSILYLATION | - |