IBS Publications Repository: Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides

DC Field	Value	Language
dc.contributor.author	Youngchan Kim	-
dc.contributor.author	Ramesh B. Dateer	-
dc.contributor.author	Sukbok Chang	-
dc.date.available	2018-07-18T02:09:15Z	-
dc.date.created	2018-03-16	-
dc.date.issued	2017-01	-
dc.identifier.issn	1523-7060	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/4821	-
dc.description.abstract	We have developed a borane-catalyzed regio- and stereoselective hydrosilylation of internal ynamides for the first time. The scope of ynamide substrates and silane reactants was broad under mild reaction conditions, affording synthetically versatile beta-silyl (Z)-enamide products. The observed stereoselectivity was reasoned to be due to the beta-silicon effect on a postulated, ketene iminium intermediate © 2016 American Chemical Society	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	AMER CHEMICAL SOC	-
dc.title	Borane-Catalyzed Selective Hydrosilylation of Internal Ynamides Leading to beta-Silyl (Z)-Enamides	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000391781600049	-
dc.identifier.scopusid	2-s2.0-85020593123	-
dc.identifier.rimsid	62475	ko
dc.date.tcdate	2018-10-01	-
dc.contributor.affiliatedAuthor	Youngchan Kim	-
dc.contributor.affiliatedAuthor	Ramesh B. Dateer	-
dc.contributor.affiliatedAuthor	Sukbok Chang	-
dc.identifier.doi	10.1021/acs.orglett.6b03485	-
dc.identifier.bibliographicCitation	ORGANIC LETTERS, v.19, no.1, pp.190 - 193	-
dc.citation.title	ORGANIC LETTERS	-
dc.citation.volume	19	-
dc.citation.number	1	-
dc.citation.startPage	190	-
dc.citation.endPage	193	-
dc.date.scptcdate	2018-10-01	-
dc.description.wostc	8	-
dc.description.scptc	8	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordPlus	TRISUBSTITUTED HOMOALLYLIC ALCOHOLS	-
dc.subject.keywordPlus	CROSS-COUPLING REACTIONS	-
dc.subject.keywordPlus	STEREOSELECTIVE HYDROSILYLATION	-
dc.subject.keywordPlus	ALKYNE HYDROSILYLATION	-
dc.subject.keywordPlus	TRANS-HYDROSILYLATION	-
dc.subject.keywordPlus	ORGANIC-SYNTHESIS	-
dc.subject.keywordPlus	TERMINAL ALKYNES	-
dc.subject.keywordPlus	VINYL CATIONS	-
dc.subject.keywordPlus	B(C6F5)(3)-CATALYZED HYDROSILYLATION	-
dc.subject.keywordPlus	REGIOSELECTIVE HYDROSILYLATION	-