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Direct diversification of unmasked quinazolin-4(3H)-ones through orthogonal reactivity modulation
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- Title
- Direct diversification of unmasked quinazolin-4(3H)-ones through orthogonal reactivity modulation
- Author(s)
- Jae Bin Lee; Mi Eun Kang; Joohee Kim; Chang Young Lee; Jung-Min Kee; Kyungjae Myung; Jang-Ung Park; Sung You Hong
- Publication Date
- 2017-09
- Journal
- CHEMICAL COMMUNICATIONS, v.53, no.75, pp.10394 - 10397
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- Here we report a set of direct functionalization methods of unmasked 2-phenylquinazolin-4(3H)-ones, a privileged alkaloid core, without the installation/removal event of protecting groups or exogenous coordinating moieties. Divergent pathways were modulated with transition-metal catalysts by suppressing competitive reactivities, leading to N-arylation, annulative pi-extension, or C-H fluorination. This journal is © The Royal Society of Chemistry 2017
- ISSN
- 1359-7345
- Appears in Collections:
- Center for Genomic Integrity(유전체 항상성 연구단) > 1. Journal Papers (저널논문)
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