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Direct diversification of unmasked quinazolin-4(3H)-ones through orthogonal reactivity modulation

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Title
Direct diversification of unmasked quinazolin-4(3H)-ones through orthogonal reactivity modulation
Author(s)
Jae Bin Lee; Mi Eun Kang; Joohee Kim; Chang Young Lee; Jung-Min Kee; Kyungjae Myung; Jang-Ung Park; Sung You Hong
Publication Date
2017-09
Journal
CHEMICAL COMMUNICATIONS, v.53, no.75, pp.10394 - 10397
Publisher
ROYAL SOC CHEMISTRY
Abstract
Here we report a set of direct functionalization methods of unmasked 2-phenylquinazolin-4(3H)-ones, a privileged alkaloid core, without the installation/removal event of protecting groups or exogenous coordinating moieties. Divergent pathways were modulated with transition-metal catalysts by suppressing competitive reactivities, leading to N-arylation, annulative pi-extension, or C-H fluorination. This journal is © The Royal Society of Chemistry 2017
URI
https://pr.ibs.re.kr/handle/8788114/4173
ISSN
1359-7345
Appears in Collections:
Center for Genomic Integrity(유전체 항상성 연구단) > Journal Papers (저널논문)
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