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Reversible photoreduction of Cu(II)-coumarin metal-organic polyhedra

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Title
Reversible photoreduction of Cu(II)-coumarin metal-organic polyhedra
Author(s)
Jaeyeon Bae; Kangkyun Baek; Daqiang Yuan; Wooram Kim; Kimoon Kim; Hong-Cai Zhou; Jinhee Park
Publication Date
2017-08
Journal
CHEMICAL COMMUNICATIONS, v.53, no.66, pp.9250 - 9253
Publisher
ROYAL SOC CHEMISTRY
Abstract
We report a new approach for photoinduced reduction of Cu2+ that will enrich the structural diversity of coordination complexes and be a valuable contributor to the development of Cu+/Cu0-based catalysts. To realize controlled Cu2+ reduction, coumarin as a triplet quencher of excited benzophenone was tethered to Cu(ii)-metal-organic polyhedra (MOPs). The photoinduced catalytic activity of the coumarin-MOPs was also examined in a Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC). © 2017 The Royal Society of Chemistry
URI
https://pr.ibs.re.kr/handle/8788114/3847
DOI
10.1039/c7cc04799a
ISSN
1359-7345
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > 1. Journal Papers (저널논문)
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