BROWSE

Related Scientist

Researcher

다차원 탄소재료 연구단
다차원 탄소재료 연구단
more info

A Ring-Opening Metathesis Polymerization Catalyst That Exhibits Redox-Switchable Monomer Selectivities

Cited 8 time in webofscience Cited 0 time in scopus
141 Viewed 3 Downloaded
Title
A Ring-Opening Metathesis Polymerization Catalyst That Exhibits Redox-Switchable Monomer Selectivities
Author(s)
Dominika N. Lastovickova; Huiling Shao; Gang Lu; Peng Liu; Christopher W. Bielawski
Publication Date
2017-05
Journal
CHEMISTRY-A EUROPEAN JOURNAL, v.23, no.25, pp.5994 - 6000
Publisher
WILEY-V C H VERLAG GMBH
Abstract
A ring-opening metathesis polymerization catalyst supported by a redox-active N-heterocyclic carbene was synthesized and found to undergo reversible reduction. In its neutral form, the catalyst polymerized 1,5-cis,cis-cyclooctadiene at a higher rate than that of a norbornene derivative; however, upon reduction, the selectivity was found to reverse. Utilizing this oxidation state dependent selectivity, a series of copolymers with controlled compositions, microstructures, and physical properties were prepared by redox-switching the catalyst over the course of a series of polymerization reactions. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/3690
ISSN
0947-6539
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
Files in This Item:
6. Lastovickova_et_al-2017-Chemistry_-_A_European_Journal.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse