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Impact of Carboxyl Groups in Graphene Oxide on Chemoselective Alcohol Oxidation with Ultra-Low Carbocatalyst Loading

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dc.contributor.authorYan Cuiko
dc.contributor.authorYoung Hee Leeko
dc.contributor.authorJung Woon Yangko
dc.date.available2017-09-05T05:00:35Z-
dc.date.created2017-07-18ko
dc.date.issued201706ko
dc.identifier.issn2045-2322ko
dc.identifier.urihttp://pr.ibs.re.kr/handle/8788114/3674ko
dc.description.abstractA highly efficient and simple chemoselective aerobic oxidation of primary alcohols to either aldehydes or carboxylic acids in the presence of nitric acid was developed, utilising 5 wt% graphene oxide as a carbocatalyst under ambient reaction conditions. Carboxylic acid functional groups on graphene oxides played a vital role in carbocatalyst activity, greatly influencing both the reactivity and selectivity. We also applied this protocol to a variant of the Knoevenagel condensation for primary alcohols and malonates with a secondary amine co-catalyst via cooperative catalysis. © The Author(s) 2017ko
dc.languageENGko
dc.publisherNATURE PUBLISHING GROUPko
dc.titleImpact of Carboxyl Groups in Graphene Oxide on Chemoselective Alcohol Oxidation with Ultra-Low Carbocatalyst Loadingko
dc.typeARTICLEko
dc.type.rimsAko
dc.identifier.wosid000402957400027ko
dc.identifier.scopusid2-s2.0-85020625603ko
dc.identifier.pid343null
dc.description.wostc2-
dc.date.scptcdate2018-10-01-
dc.identifier.doi10.1038/s41598-017-03468-4ko
dc.identifier.bibliographicCitationSCIENTIFIC REPORTS, v.7, no., pp.3146 -ko
dc.date.tcdate2018-10-01-
dc.description.scptc2-
dc.type.docTypeArticle-
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Center for Integrated Nanostructure Physics(나노구조물리 연구단) > Journal Papers (저널논문)
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