Impact of Carboxyl Groups in Graphene Oxide on Chemoselective Alcohol Oxidation with Ultra-Low Carbocatalyst Loading
DC Field | Value | Language |
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dc.contributor.author | Yan Cui | - |
dc.contributor.author | Young Hee Lee | - |
dc.contributor.author | Jung Woon Yang | - |
dc.date.available | 2017-09-05T05:00:35Z | - |
dc.date.created | 2017-07-18 | ko |
dc.date.issued | 2017-06 | - |
dc.identifier.issn | 2045-2322 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/3674 | - |
dc.description.abstract | A highly efficient and simple chemoselective aerobic oxidation of primary alcohols to either aldehydes or carboxylic acids in the presence of nitric acid was developed, utilising 5 wt% graphene oxide as a carbocatalyst under ambient reaction conditions. Carboxylic acid functional groups on graphene oxides played a vital role in carbocatalyst activity, greatly influencing both the reactivity and selectivity. We also applied this protocol to a variant of the Knoevenagel condensation for primary alcohols and malonates with a secondary amine co-catalyst via cooperative catalysis. © The Author(s) 2017 | - |
dc.language | 영어 | - |
dc.publisher | NATURE PUBLISHING GROUP | - |
dc.title | Impact of Carboxyl Groups in Graphene Oxide on Chemoselective Alcohol Oxidation with Ultra-Low Carbocatalyst Loading | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000402957400027 | - |
dc.identifier.scopusid | 2-s2.0-85020625603 | - |
dc.identifier.rimsid | 59785 | ko |
dc.date.tcdate | 2018-10-01 | - |
dc.contributor.affiliatedAuthor | Young Hee Lee | - |
dc.identifier.doi | 10.1038/s41598-017-03468-4 | - |
dc.identifier.bibliographicCitation | SCIENTIFIC REPORTS, v.7, no.1, pp.3146 | - |
dc.relation.isPartOf | SCIENTIFIC REPORTS | - |
dc.citation.title | SCIENTIFIC REPORTS | - |
dc.citation.volume | 7 | - |
dc.citation.number | 1 | - |
dc.citation.startPage | 3146 | - |
dc.date.scptcdate | 2018-10-01 | - |
dc.description.wostc | 2 | - |
dc.description.scptc | 2 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.subject.keywordPlus | SELECTIVE AEROBIC OXIDATION | - |
dc.subject.keywordPlus | BENZYL ALCOHOL | - |
dc.subject.keywordPlus | SUPPORTED PLATINUM | - |
dc.subject.keywordPlus | CATALYTIC-ACTIVITY | - |
dc.subject.keywordPlus | LIQUID-PHASE | - |
dc.subject.keywordPlus | NITRIC-ACID | - |
dc.subject.keywordPlus | N-BUTANE | - |
dc.subject.keywordPlus | NANOTUBES | - |
dc.subject.keywordPlus | DEHYDROGENATION | - |
dc.subject.keywordPlus | GRAPHITE | - |