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다차원 탄소재료 연구단
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A Photoswitchable Olefin Metathesis Catalyst

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Title
A Photoswitchable Olefin Metathesis Catalyst
Author(s)
Aaron J. Teator; Huiling Shao; Gang Lu; Peng Liu; Christopher W. Bielawski
Publication Date
2017-01
Journal
ORGANOMETALLICS, v.36, no.2, pp.490 - 497
Publisher
AMER CHEMICAL SOC
Abstract
A dithienylethene-functionalized N-heterocyclic carbene-Ru(II) complex was synthesized and found to undergo a reversible photoisomerization which influenced its intrinsic catalytic activity. UV-induced ring-closure enhanced the rate of ring closing metathesis reactions (k(closed)/k(opened) = 1.4-1.7) and attenuated the rate of ring-opening metathesis polymerizations (k(closed)/k(opened) = 0.56-0.66). Visible light irradiation promoted cycloreversion and restored the initial activity. The ability to switch between the isomeric states of the catalyst was also utilized to modulate the rate of ongoing olefin metathesis reactions via photoirradiation. A computational investigation revealed how steric and electronic effects separately influence the transition states adopted by each form of the catalyst and afforded activation energies that were in agreement with the relative reaction rate constants determined by experiment © 2017 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/3563
ISSN
0276-7333
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
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