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다차원 탄소재료 연구단
다차원 탄소재료 연구단
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Dendrimer-Capped Gold Nanoparticles for Highly Reliable and Robust Surface Enhanced Raman Scattering

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Title
Dendrimer-Capped Gold Nanoparticles for Highly Reliable and Robust Surface Enhanced Raman Scattering
Author(s)
Kwanghyun Kim; Jeongyeop Lee; Gyeongcheon Jo; Seungmin Shin; Jin-Baek Kim; Ji-Hyun Jang
Publication Date
2016-08
Journal
ACS APPLIED MATERIALS & INTERFACES, v.8, no.31, pp.20379 - 20384
Publisher
AMER CHEMICAL SOC
Abstract
Dendrimer-stabilized gold nanoparticles (Au-Den) were prepared by a facile solution based method for a highly reliable and robust surface enhanced Raman scattering (SERS) substrate. Au-Den was selectively attached on the surface of reduced graphene oxide (rGO) by noncovalent interactions between the Au capping dendrimer and the graphene surface. Au-Den/rGO exhibits the outstandingly stable and highly magnified Raman signal with an enhancement factor (EF) of 3.9 × 107 that enables detection of R6G dyes with concentration as low as 10 nM, retaining 95% of the Raman signal intensity after 1 year. The remarkable stability and enhancement originated not only from a simple combination of the electromagnetic and chemical mechanism of SERS but also from intensified packing density of stable Au-Den on the graphene substrate due to the firm binding between the dendrimer capped metal nanoparticles and the graphene substrate. This method is not limited to the gold nanoparticles and G4 dendrimer used herein, but also can be applied to other dendrimers and metal nanoparticles, which makes the material platform suggested here superior to other SERS substrates. © 2016 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/2985
ISSN
1944-8244
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
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