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Olefin hydroborations with diamidocarbene–BH3 adducts at room temperature

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Title
Olefin hydroborations with diamidocarbene–BH3 adducts at room temperature
Author(s)
Dominika N. Lastovickova; Christopher W. Bielawski
Subject
Carbenes, ; Diamidocarbene, ; Hydroboration, ; Lewis adducts, ; Organocatalysis
Publication Date
2016-09
Journal
CATALYSTS, v.6, no.9, pp.141
Publisher
MDPI
Abstract
An isolable N,N′-diamidocarbene (DAC) was previously shown to promote the B–H bond activation of various BH3 complexes. The resultant DAC–BH3 adducts facilitated olefin hydroborations under mild conditions and in the absence of exogenous initiators. The substrate scope for such transformations was further explored and is described herein. While organoboranes were obtained in quantitative yields from various terminal and internal olefins, use of the latter substrates resulted in intramolecular ring-expansion of the newly formed DAC–borane adducts. © 2016 by the authors; licensee MDPI, Basel, Switzerland
URI
https://pr.ibs.re.kr/handle/8788114/2976
DOI
10.3390/catal6090141
ISSN
2073-4344
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
1. catalysts-06-00141.pdfDownload

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