BROWSE

Related Scientist

cmcm's photo.

cmcm
다차원탄소재료연구단
more info

ITEM VIEW & DOWNLOAD

Olefin hydroborations with diamidocarbene–BH3 adducts at room temperature

Cited 0 time in webofscience Cited 0 time in scopus
1,318 Viewed 346 Downloaded
Title
Olefin hydroborations with diamidocarbene–BH3 adducts at room temperature
Author(s)
Dominika N. Lastovickova; Christopher W. Bielawski
Subject
Carbenes, ; Diamidocarbene, ; Hydroboration, ; Lewis adducts, ; Organocatalysis
Publication Date
2016-09
Journal
CATALYSTS, v.6, no.9, pp.141
Publisher
MDPI
Abstract
An isolable N,N′-diamidocarbene (DAC) was previously shown to promote the B–H bond activation of various BH3 complexes. The resultant DAC–BH3 adducts facilitated olefin hydroborations under mild conditions and in the absence of exogenous initiators. The substrate scope for such transformations was further explored and is described herein. While organoboranes were obtained in quantitative yields from various terminal and internal olefins, use of the latter substrates resulted in intramolecular ring-expansion of the newly formed DAC–borane adducts. © 2016 by the authors; licensee MDPI, Basel, Switzerland
URI
https://pr.ibs.re.kr/handle/8788114/2976
DOI
10.3390/catal6090141
ISSN
2073-4344
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
1. catalysts-06-00141.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse