IBS Publications Repository: Efficient synthesis of bulky N-Heterocyclic carbene ligands for coinage metal complexes

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IBS Publications RepositoryCenter for Self-assembly and Complexity(복잡계 자기조립 연구단)1. Journal Papers (저널논문)

Efficient synthesis of bulky N-Heterocyclic carbene ligands for coinage metal complexes

DC Field	Value	Language
dc.contributor.author	Youngsuk Kim	-
dc.contributor.author	Yonghwi Kim	-
dc.contributor.author	Moon Young Hur	-
dc.contributor.author	Eunsung Lee	-
dc.date.available	2016-11-29T08:18:29Z	-
dc.date.created	2016-08-19	-
dc.date.issued	2016-10	-
dc.identifier.issn	0022-328X	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/2970	-
dc.description.abstract	A facile and efficient route to synthesize sterically bulky N-heterocyclic carbenes with high percent buried volumes has been developed. The method involves three steps from commercial reagents and produced the NHC precursors with approximately 40% overall yield without column chromatography. The free carbenes were isolated as confirmed by X-ray crystallography and 13C NMR peak at 213 ppm corresponding to the carbene carbons. The Cu(I), Ag(I), and Au(I) chloride complexes supported by the NHC ligands were successfully synthesized and fully characterized including X-ray crystallography. © 2016 Elsevier B.V	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	ELSEVIER SCIENCE SA	-
dc.subject	N-heterocyclic carbene, Coinage metal complex, Ligand design, Percent buried volume	-
dc.title	Efficient synthesis of bulky N-Heterocyclic carbene ligands for coinage metal complexes	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000382200300001	-
dc.identifier.scopusid	2-s2.0-84980407640	-
dc.identifier.rimsid	56263	ko
dc.date.tcdate	2018-10-01	-
dc.contributor.affiliatedAuthor	Youngsuk Kim	-
dc.contributor.affiliatedAuthor	Yonghwi Kim	-
dc.contributor.affiliatedAuthor	Moon Young Hur	-
dc.contributor.affiliatedAuthor	Eunsung Lee	-
dc.identifier.doi	10.1016/j.jorganchem.2016.07.023	-
dc.identifier.bibliographicCitation	JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.820, pp.1 - 7	-
dc.citation.title	JOURNAL OF ORGANOMETALLIC CHEMISTRY	-
dc.citation.volume	820	-
dc.citation.startPage	1	-
dc.citation.endPage	7	-
dc.date.scptcdate	2018-10-01	-
dc.description.wostc	6	-
dc.description.scptc	6	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-
dc.subject.keywordPlus	CROSS-COUPLING REACTIONS	-
dc.subject.keywordPlus	H BOND FUNCTIONALIZATION	-
dc.subject.keywordPlus	CATALYTIC APPLICATIONS	-
dc.subject.keywordPlus	BURIED VOLUME	-
dc.subject.keywordPlus	IPR-ASTERISK	-
dc.subject.keywordPlus	C-N	-
dc.subject.keywordPlus	CHEMISTRY	-
dc.subject.keywordPlus	CHLORIDE	-
dc.subject.keywordPlus	DESIGN	-
dc.subject.keywordPlus	NHC	-
dc.subject.keywordAuthor	N-heterocyclic carbene	-
dc.subject.keywordAuthor	Coinage metal complex	-
dc.subject.keywordAuthor	Ligand design	-
dc.subject.keywordAuthor	Percent buried volume	-