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다차원 탄소재료 연구단
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Diamidocarbene Induced B-H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents

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Title
Diamidocarbene Induced B-H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents
Author(s)
Dominika N. Lastovickova; Christopher W. Bielawski
Publication Date
2016-03
Journal
ORGANOMETALLICS, v.35, no.5, pp.706 - 712
Publisher
AMER CHEMICAL SOC
Abstract
Enabled by its enhanced electrophilicity and attenuated nucleophilicity, an N,N'-diamidocarbene (DAC) was found to promote the B-H bond activation of various BH3 complexes and the B-B bond of bis(pinacolato)diboron, constituting the first such examples for an isolable carbene. The resultant DAC-BH3 adducts datively coordinated to Lewis bases (i.e., dimethyl sulfide, trimethylamine, or pyridine) and facilitated the hydroboration of various olefins under mild conditions and in the absence of exogenous initiators. © 2016 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/2701
ISSN
0276-7333
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
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