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Facet-controlled hollow Rh2S3 hexagonal nanoprisms as highly active and structurally robust catalysts toward hydrogen evolution reaction

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Title
Facet-controlled hollow Rh2S3 hexagonal nanoprisms as highly active and structurally robust catalysts toward hydrogen evolution reaction
Author(s)
Donghwan Yoon; Bora Seo; jaeyoung Lee; Kyoung Sik Nam; Byeongyoon Kim; Suhyun Park; Hionsuck Baik; Sang Hoon Joo; Kwangyeol Lee
Publication Date
2016-03
Journal
ENERGY & ENVIRONMENTAL SCIENCE, v.9, no.3, pp.850 - 856
Publisher
ROYAL SOC CHEMISTRY
Abstract
Developing highly active and structurally robust electrocatalysts for hydrogen evolution reaction (HER) is of paramount importance for sustainable and clean production of hydrogen. Metal sulphides exposing catalytically active sites, in particular, have been actively pursued as advanced HER catalysts. Herein we report high-performance Rh2S3-based HER catalysts with excellent activity and durability. Hollow Rh2S3 hexagonal nanoprisms with controlled size and thickness could be conveniently prepared by one-step formation of core-shell nanoprisms followed by the etching of the core, and they show high surface areas and highly exposed edge sites. The hollow Rh2S3 nanoprisms exhibit very high HER activity and excellent stability under harsh acidic conditions. © The Royal Society of Chemistry 2016
URI
https://pr.ibs.re.kr/handle/8788114/2590
DOI
10.1039/c5ee03456f
ISSN
1754-5692
Appears in Collections:
Center for Molecular Spectroscopy and Dynamics(분자 분광학 및 동력학 연구단) > 1. Journal Papers (저널논문)
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Facet-controlled hollow_Kwangyeol Lee(승인완료).pdfDownload

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