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복잡계자기조립연구단
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The guest-dependent thermal response of the flexible MOF Zn2(BDC)2(DABCO)

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dc.contributor.authorYonghwi Kim-
dc.contributor.authorRitesh Haldar-
dc.contributor.authorKim H.-
dc.contributor.authorJaehyoung Koo-
dc.contributor.authorKimoon Kim-
dc.date.available2016-06-13T09:07:52Z-
dc.date.created2016-03-17-
dc.date.issued2016-03-
dc.identifier.issn1477-9226-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/2524-
dc.description.abstractThe guest-dependent thermal response of the flexible MOF Zn2(BDC)2(DABCO) (1) has been studied. A series of temperature-dependent single crystallographic analyses revealed inherent structural thermal responses of 1. The guest-free framework 1 exhibited interesting thermal responses including anisotropic thermal expansion (negative thermal expansion (NTE) along the a- and b-axes, positive thermal expansion (PTE) along the c-axis) and disorder-order phase transition. In addition, inclusion of guest molecules (DMF and benzene) brought distinct thermal responses to 1 from host-guest interactions. 1·4DMF showed altered thermal responses, presenting disorder-order phase transitions at a higher temperature and PTE along the a- and b-axes. Meanwhile, 1·3benzene displayed a quite different type of thermal response such as a hinge like motion (breathing) without a symmetry change. © The Royal Society of Chemistry 2016-
dc.description.uri1-
dc.language영어-
dc.publisherROYAL SOC CHEMISTRY-
dc.titleThe guest-dependent thermal response of the flexible MOF Zn2(BDC)2(DABCO)-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000371710500016-
dc.identifier.scopusid2-s2.0-84959571863-
dc.identifier.rimsid22847ko
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorYonghwi Kim-
dc.contributor.affiliatedAuthorRitesh Haldar-
dc.contributor.affiliatedAuthorJaehyoung Koo-
dc.contributor.affiliatedAuthorKimoon Kim-
dc.identifier.doi10.1039/c5dt03710g-
dc.identifier.bibliographicCitationDALTON TRANSACTIONS, v.45, no.10, pp.4187 - 4192-
dc.citation.titleDALTON TRANSACTIONS-
dc.citation.volume45-
dc.citation.number10-
dc.citation.startPage4187-
dc.citation.endPage4192-
dc.date.scptcdate2018-10-01-
dc.description.wostc14-
dc.description.scptc17-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
Appears in Collections:
Center for Self-assembly and Complexity(복잡계 자기조립 연구단) > 1. Journal Papers (저널논문)
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