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나노물질 및 화학반응 연구단
나노물질 및 화학반응 연구단
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Anomalous rapid defect annihilation in self-assembled nanopatterns by defect melting

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Title
Anomalous rapid defect annihilation in self-assembled nanopatterns by defect melting
Author(s)
Bong Hoon Kim; Park S.J.; Hyeong Min Jin; Ju Young Kim; Son S.-W.; Kim M.-H.; Koo C.M.; Shin J.; Kim J.U.; Sang Ouk Kim
Publication Date
2015-02
Journal
NANO LETTERS, v.15, no.2, pp.1190 - 1196
Publisher
AMER CHEMICAL SOC
Abstract
Molecular self-assembly commonly suffers from dense structural defect formation. Spontaneous defect annihilation in block copolymer (BCP) self-assembly is particularly retarded due to significant energy barrier for polymer chain diffusion and structural reorganization. Here we present localized defect melting induced by blending short neutral random copolymer chain as an unusual method to promote the defect annihilation in BCP self-assembled nanopatterns. Chemically neutral short random copolymer chains blended with BCPs are specifically localized and induce local disordered states at structural defect sites in the self-assembled nanopatterns. Such localized “defect melting” relieves the energy penalty for polymer diffusion and morphology reorganization such that spontaneous defect annihilation by mutual coupling is anomalously accelerated upon thermal annealing. Interestingly, neutral random copolymer chain blending also causes morphology-healing self-assembly behavior that can generate large-area highly ordered 10 nm scale nanopattern even upon poorly defined defective prepatterns. Underlying mechanisms of the unusual experimental findings are thoroughly investigated by three-dimensional self-consistent field theory calculation.
URI
https://pr.ibs.re.kr/handle/8788114/2112
ISSN
1530-6984
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > Journal Papers (저널논문)
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