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Nanochemical Investigation of Degradation in Organic-Inorganic Hybrid Perovskite Films Using Infrared Nanoscopy

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Title
Nanochemical Investigation of Degradation in Organic-Inorganic Hybrid Perovskite Films Using Infrared Nanoscopy
Author(s)
Yu, Hyang Mi; Oh, Hye Min; Park, Dae Young; Mun Seok Jeong
Publication Date
2020-02
Journal
The Journal of Physical Chemistry C, v.124, no.6, pp.3915 - 3922
Publisher
American Chemical Society
Abstract
The degradation of organic-inorganic hybrid perovskite (OHP) films is a crucial issue in OHP optoelectronics. Herein, we investigate the degradation process of OHP films by simultaneous measurement of topography and infrared absorption mapping images using photothermal induced resonance spectroscopy. By tracking the intensity of molecular vibration, we found that oxygen and moisture are easily attached at the grain boundary (GB) rather than at the grain interior of the OHP film. These data are well matched with photoluminescence (PL) mapping images, which show that the PL intensity of PbI2 as an indicator of degradation is relatively intense at the GB. Thus, by using correlated structural, chemical, and optical analyses, we confirm that the degradation of the OHP film is initiated at the GB through the attached oxygen molecules and moisture. We expect that this study will contribute to solving the degradation issue and enhancing the stability of OHP optoelectronics.
URI
https://pr.ibs.re.kr/handle/8788114/15527
DOI
10.1021/acs.jpcc.0c00143
ISSN
1932-7447
Appears in Collections:
Center for Integrated Nanostructure Physics(나노구조물리 연구단) > 1. Journal Papers (저널논문)
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