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Molecular photothermal effects, diffusion, and sample flow in time-resolved spectroscopy and microscopy

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Title
Molecular photothermal effects, diffusion, and sample flow in time-resolved spectroscopy and microscopy
Author(s)
Minhaeng Cho
Publication Date
2023-12
Journal
Journal of Chemical Physics, v.159, no.22
Publisher
American Institute of Physics Inc.
Abstract
Time-resolved pump-probe and two-dimensional spectroscopy are widely used to study ultrafast chemical and biological processes in solutions. However, the corresponding signals at long times can be contaminated by molecular photothermal effects, which are caused by the nonradiative heat dissipation of photoexcited molecules to the surroundings. Additionally, molecular diffusion affects the transient spectroscopic signals because photoexcited molecules can diffuse away from the pump and probe beam focuses. Recently, a theoretical description of molecular photothermal effects on time-resolved IR spectroscopy was reported. In this work, I consider the molecular photothermal process, molecular diffusion, and sample flow to develop a generalized theoretical description of time-resolved spectroscopy. The present work can be used to interpret time-resolved spectroscopic signals of electronic or vibrational chromophores and understand the rate and mechanisms of the conversion of high-frequency molecular electronic and vibrational energy to solvent kinetic energy in condensed phases. © 2023 Author(s).
URI
https://pr.ibs.re.kr/handle/8788114/14563
DOI
10.1063/5.0181086
ISSN
0021-9606
Appears in Collections:
Center for Molecular Spectroscopy and Dynamics(분자 분광학 및 동력학 연구단) > 1. Journal Papers (저널논문)
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